Reduction Reactions
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Reduction Reactions
Cyanohydrin Reaction
Osazone Reaction
Phenyl hydrazine is a mild oxidizing agent which reacts with the aldehyde group of glucose to form osazone, a bridge yellow crystalline substance. It is a specific test of identification of sugars.
Furfurals
Concentrated mineral acids cause dehydration of monosaccharides to form furfural compounds which give a coloured product when treated with phenol. However, sugars are stable to dilute acids.
Enolization
Dilute alkali brings about a rearrangement of sugars at the anomeric carbon and the one next to it even at room temperature. These are isomerization reactions. For example, D – glucose on treatment with dilute alkali forms an equilibrium mixture of D-glucose on , D – mannose and D – fructose through formation of enediol intermediates.