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Reduction  Reactions


Monosaccharides (both aldoses and ketoses) can be reduced to corresponding polyhydroxy alcohols by reducing agents such as sodium borohydride (NaBH4), Sodium amalgam, etc. for example, D-glucose is reduced to D-glucitol (sorbitol),  D-mannose to mannitol and fructose to mannitol and glucitol.

Reduction Reactions


reduction Reactions

Cyanohydrin Reaction


Glucose reacts with regents like HCN, which is a typical aldehyde reaction.



Cyanohydrin Reaction


Osazone Reaction

Phenyl hydrazine is a mild oxidizing agent which reacts with the aldehyde group of glucose to form osazone, a bridge yellow crystalline substance. It is a specific test of identification of sugars.

Furfurals


Concentrated mineral acids cause dehydration of monosaccharides to form furfural compounds which give a coloured product when treated with phenol. However, sugars are stable to dilute acids.


Furfurals

 

furfurals

 

Enolization

Dilute alkali brings about a rearrangement of sugars at the anomeric carbon and the one next to it even at room temperature. These are isomerization reactions. For example, D – glucose on treatment with dilute alkali forms an equilibrium mixture of D-glucose on , D – mannose and D – fructose through formation of enediol intermediates.

Enolization

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